单体浓度对聚合物稳定铁电液晶稳定性的影响

制备了不同单体浓度的聚合物稳定铁电液晶器件,测试了震动实验和热稳定实验前后样品的排列织构、电光特性和对比度.用原子力显微镜研究了各样品的聚合物形貌,表明在器件内部形成了沿摩擦方向延伸的聚合物网络,并且随着单体含量的增加聚合物网络更加致密.由于聚合物网络体锚定的引入,使得铁电液晶分子在外力和温度场下的运动受到限制,聚合物体锚定的增强使聚合物稳定铁电液晶的稳定性也逐渐提高.实验结果表明,单体含量为4％时,聚合物稳定铁电液晶的抗震性和热稳定性良好,电光曲线为无阈值“V”字型,对比度达150∶1.     

基于激光微加工的新型光纤法布里-珀罗折射率传感器

提出了一种新型的光纤法布里-珀罗(F-P)折射率传感器,该传感器由单模光纤头端面和靠近该端面的由157 nm激光加工而成的短空气腔构成.短空气腔两个端面的反射光和光纤头端面的反射光发生干涉形成了传感器的反射谱干涉条纹.干涉条纹的对比度受光纤头端面外部的折射率影响,在干涉条纹包络的波谷处具有最大的对比度,外部待测折射率可通过计算该处的对比度得到.传感器对温度不敏感同,测量范围广.在1.33至1.441范围内,折射率灵敏度约为27 dB,分辨率约为1.12X10-4;在1.45～1.62范围内.折射率灵敏度约为24 dB,分辨率约为1.26×10-4.     

轴向隐失波激励的回音壁模式光纤激光器

采用轴向隐失波激励增益的方式,使激光增益区域局限在光纤回音壁模式的模场区域内,显著地降低了回音壁模式光纤激光辐射的抽运阈值,由此形成一种低阈值的回音壁模式光纤激光器.在微焦耳量级的低抽运能量条件下,用回音壁模式光纤激光器研究了激光染料的浓度效应.实验结果表明,随着激光染料浓度的增加,回音壁模式激光辐射的波长向长波方向移动,激光波长范围变宽.用回音壁模式染料激光的四能级模型得到激光上能级和所有能级上的分子数比值γ(λ)曲线后,很好地解释了实验结果.低抽运阈值的回音壁模式光纤激光器,为研究液体激光现象提供了极为便利的手段.     

An Approach to Extract the Spin Transfer to ∧in Polarized Proton--Proton Collision

We introduce an approach to extract the spin transfer to A in polarized proton-proton collision, based on the relation between single spin asymmetry and the polarization of A production. With 4 × 10^6 ∧ events simulated for a PHENIX detector system, DLL = 0.1598 ± 0.0343 is retrieved by the approach and it agrees very well with the input value of 0.1429. The approach is further tested and confirmed with ‘bunch shuffling＇ method for the simulated events as well as experimental events collected at PHENIX in 2003. It is concluded that one can correctly extract the spin transfer without detailed understanding of acceptance correction even if the correction is significantly large in PHENIX experiment by using the approach described here. The method can be generally used for spin transfer study.     

The roles of “ammonium” and “hydrogen-bond” protons in single crystals of the superionic conductor NH4HSeO4 by H NMR relaxation

The variations with temperature of the line-shape, spin-lattice relaxation time, T₁, and spin-spin relaxation time, T₂, of the ¹H nuclei in NH₄HSeO₄ single crystals were investigated, and with these ¹H NMR results we were able to distinguish the crystals’ “ammonium” and “hydrogen-bond” protons. The line width of the signal due to the ammonium protons abruptly narrows near the temperature of the superionic phase transition, T_SI, which indicates that they play an important role in this phase transition. The ¹H T₁ for NH₄⁺ and HSeO₄⁻ in NH₄HSeO₄ do not change significantly near the ferroelectric phase transition of T_C1 (=250 K) and the incommensurate phase transition of T_i (=261 K), whereas they change near the temperature of the superionic phase transition T_SI (=400 K). Our results indicate that the main contribution to the low-temperature phase transition below T_SI is that of the molecular motion of ammonium and hydrogen-bond protons, and the main contribution to the conductivity at high temperatures above T_SI is the breaking of the O-H?O bonds and the formation of new H- bonds in HSeO₄⁻. In addition, we compare these results with those for the NH₄HSO₄ and (NH₄)₃H(SO₄)₂ single crystals, which have similar hydrogen-bonded structure.     

超临界CO2协助三单体接枝改性聚丙烯

利用超临界二氧化碳(SC CO2)作为单体的溶剂和聚丙烯的溶胀剂, 通过自由基接枝聚合合成了聚丙烯与丙烯酸、甲基丙烯酸甲酯以及马来酸酐的接枝产物PP-g-(AA-MMA-MAH). 在单体的选择上采取软、硬单体复配的方式来调节链的柔韧性. 考察了溶胀条件、接枝条件以及单体配比对接枝反应的影响, 研究结果表明, PP和单体以及引发剂在7.74 MPa、47 ℃下溶胀5 h后, 75 ℃下反应3 h时接枝率为4.31%, 接枝效率可达71.83%. 产品表征说明单体均匀地接枝到聚丙烯颗粒上; 改性后聚丙烯水润湿角降低, 亲水性能得到明显改善; 接枝单体的引入提高了PP的热稳定性.     

Mo2C膜表面高度和高差分布规律研究

介绍了金属有机气相沉积（ＭＯＣＶＤ）制备Ｍｏ２Ｃ功能膜的过程和对膜表面粗糙度的测量结果;在测量基础上进行统计,找出Ｍｏ２Ｃ膜表面高度和高差分布规律;将ＤＴ２模型推广,进行２＋１维计算机模拟,作出Ｍｏ２Ｃ膜表面３维模拟图。结果表明：实验测得的高度和高差统计分布与计算机模拟的结果一致。     

CO氧化反应耦合下SrFe1.125Co0.375Oy的氧渗透行为

报道ＳｒＦｅ１．１２５Ｃｏ０．３７５Ｏｙ致密陶瓷膜在高氧梯度下的氧渗透行为。将膜的一端置于空气中,另一端引入ＣＯ,通过ＣＯ的氧化反应降低氧分压,增大膜两端的氧分压梯度。研究发现：９００℃时氧渗透率高达１６．０＊１０＊－７ｍｏｌ／ｃｍ＾２ｓ。在８５０℃以上,氧渗透率与温度的依赖关系不显著,而氧渗透量与ＣＯ分压成线形关系,并且与膜的厚变化基本无关,这表明在该膜材料的渗透过程是受表面反应控制的。     

一类时滞微分方程解的振动准则

本文建立了一类时滞微分方程一切解振动的必要充分条件     

六方沸石分子筛催化剂用于异丁烷与丁烯的烷基化

异构烷烃与烯烃的烷基化是炼油装置制备高辛烷值汽油添加剂的重要途径.目前传统工艺仍使用矿物酸如硫酸或氢氟酸作催化剂,由于该工艺存在着产物分离困难、设备腐蚀严重及环境污染问题,从60年代起国内外开始致力于新型固体酸催化剂的研究与开发工作,已报道的有离子交换树脂[1]、分子筛催化剂[2]及SO=4/MxOy型催化剂[3]等,在分子筛催化剂中已报道的有立方沸石[4]β-分子筛[5]、ZSM系列[5]、分子筛[5]、蒙脱石[5]及MCM-22[6]等,这些催化剂的共性是催化活性较高,但失活较快.目前对分子筛催化剂的研究主要集中在改进的立方沸石体系,而六方沸石催化剂催化异丁烷与丁烯烷基化反应尚未见报道.